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History

During the same year that Seebeck discovered thermoelectricity, Humphrey Davy
(1778-1829) would announce that metal resistivity had a clear dependance on temperature. Fifty years later, William Seamens
used platinum in a resistance thermometer. This favourable choice standardized all future resistance thermometers with
platinum being the key element for high precision temperature measurement. The Platinum Resistance Temperature Detector
or PRTD is now used to measure from the triple point of hydrogen (-259,34°C) to the freezing point of silver
(961,78°C). Platinum is particularly convenient for this type of temperature range, as it maintains an excellent
stability which will hardly alter after repeat use.
In 1932, C.H. Meyers proposed construction of a Platinum Resistance Temperature Detector (RTD) composed of a platinum wire
wrapped around a mica support core inside a glass tube. This type of construction minimizes the wire tension and maximizes
resistance. Even thought it is a very stable assembly the thermal contact between the platinum and the measurement point
is weak and a diminished temperature response time is the result. Due to the structure's fragility, this type of RTD is
used mainly in laboratories today.
Another labaratory tool replaced Meyer's concept. This "bird cage" element (Figure 1) was proposed by Evans and Burns.
Resistance constraints provoked by time and temperature were reduced to a minimum and this style RTD became the labaratory
norm. However, due to it's fragile nature and sensitivity to vibrations, it was not suitable for industrial applications.

More solidly constructed RTDs are shown in figures 2, 3, and 4. A bifilament platinum wire is wound on a ceramic or
glass core. This winding reduces magnetic induction and noise. Once the wire is wound on the core, the assembly is
sealed by molten glass. As long as the dilation coefficient of the platinum wire and ceramic core are not exactly the
same, the platinum wire's dilation will result in a resistance change, sometimes consequenting in a permanent change
of the wire's resistance. Versions exist of RTDs that offer a compromise between the "bird cage" and the sealed spiral
wound styles. This approach employs a rolled spiral of platinum wire wound on a ceramic cylinder and maintained by a

Modern fabrication techniques use a platinum or other metallic film deposited on a ceramic substrate that has been
water jet cut, laser cut, and sealed. This film RTD offers a substantial savings in assembly time and high resistance
for it's size. Due to advanced technological fabrication, these devices are very small and have high thermal conductivity
allowing a quick temperature change response time.
Film RTDs are less stable than wire filament wound RTDs but have a smaller size advantage, lower production time advantage,
and are user friendly. These advantages have made this style RTD very popular and widely used.

Metals

All metals produce a postive change in resistance for a positive change in temperature. This is the principal function
of an RTD. System error is greatly reduced when the nominal value of the RTD resistance is high; this implies that a
metallic wire has a high resistivity.
| RTD Metals Resistivity |
| Metal |
Symbol |
Resistivity Ω•cm/f |
Resistivity Ω•mm2/m |
Resistivity siemens |
| Gold |
Au |
13 |
2,1612e-2 |
4,6272e+7 |
| Silver |
Ag |
8,8 |
1,4629e-2 |
6,8356e+7 |
| Copper |
Cu |
9,26 |
1,5394e-2 |
6,496e+7 |
| Platinum |
Pt |
59 |
9,8083e-2-2 |
1,0195e+7 |
| Tungsten |
W |
30 |
4,9873e-2 |
2,0051e+7 |
| Nickel |
Ni |
36 |
5,9847e-2 |
1,6709e+7 |
Due to their low resistivity, gold and silver are rearely used as RTD elements. Tungsten has a relatively
high resistivity but is mainly used in applications that require an extremely high temperature measurement
although the wire is very fragile and RTD construction difficult. Copper is used as an alternative to the
popular platinum due to it's linearity and more economical pricing. It's low resistivity requires a longer
length of wire than a standard platinum RTD and is limited to temperature measurement up to approx. 120°C.
The most common RTDs are constructed with platinum, nickel, ar a nickel alloy blend. Nickel alloy wires are
economical but are limited to a specific temperature range, are not linear, and have tendancy to drift over
time. For precise temperature measurement, platinum is the obvious choice.
Temperature coefficient

The standard temperature coefficient DIN 43760 of platinum wire is: α = 0.00385. For a resistance of 100
ohms at 0°C, this corrsponds to + 0,385 ohm per °C which is the average curve from 0°C to 100°C.
There exists a large variety of RTD's that have different coeffcients and ohm values at 0°C. However, the most
common RTD is that with the above example, PT100, with a coeffficent of 0.00385 and an ohm value of 0°C at 100
ohms. This is what the following pages' calculations and explanations will be based on.
| International Standards DIN 43760 (IEC 751, BS-1904, JIS C1604) |
| Parameter |
Class A |
Class B |
| R0 |
100Ω ±0,06% |
100Ω ±0,12% |
| Alpha, α |
0,00385 ±0,000063 |
0,00385 ±0,000063 |
| Range |
-200°C à 650°C |
-200°c à 850°C |
| Res, RT |
±(.06+.0008|T|-2e-7T2) |
±(.12+.0019|T|-6e-7T2) |
| Temp, T |
±(0.3+0.002|T|)°C |
±(0.3+0.005|T|)°C |
Resistance Measurement


could be several ohms or even 10 ohms. This may cause significate errors if the temperature reading. A 10
ohms difference can cause an error of 10/0,385 so approximately 26 °C in this case.
Wheatstone Bridge


bridge model is shown here, is an indirect indication of the RTD resistivity. The bridge requires 4 parrallel
branches; 1 exterior electrical source and 3 resistors with a zero temperature coefficient.
3 Wires Bridge

To avoid subjecting the 3 resistors to the same temperature of the RTD, we sperate them from the bridge with a

pair of connection wires (Figure 7).
These wires recreate the problem that we have seen before: the resistance of the wires affects the temperature
reading. This effect can be reduced to a minimum by employing the configuration of a 3 wires bridge (Figure 8).
If wires A and B are the same length, their resistance effect will be annulled due to the fact that both are on
an opposite side of the bridge. The third wire, C, is the measuring wire where there is no circulating current.

The Wheatstone bridge represented in Figure 8 creates a non linear relation between the resistance change and the
change in tension in the bridge. This will require an additional equation to convert the tension measurement of
the bridge into an RTD equivalent resistance.
4 Wires Measurement


can circulate in the tension measurement wires, there will be no drop in tension and therefore no error in resistance
measurement. The tension read on the voltmeter is directly proportional to the resitance value of the RTD.
The three resitances of the bridge are replaced by a resitance of reference permitting to know, with precision, the
generated current (Figure 9). The inconvenience is that it requires an additional wire than the 3 wire bridge. It is
a small price to pay in order to obtain exact resitance measurements.
Even though it has excellent precision, the 4 wire resistance measurement, like all other measurements, will always be
affected by errors and the results will be to try and minimize these errors by taking all the necessary precautions.
Possible Errors and Precautions

The RTD is susceptible to three types of errors:
• The inherannt tolerances to resitance of the RTD itself,
• The gradient in temperature between the thermometer and the measuring point,
• The faults and errors in that are present in the extension connection between the sensor and the measurement instrument.
Some sources of error are electrical and others are the result of the mecanical construction of the RTD. Potential source
errors include the interchangeability and conformity: The conformity indicates the quantity that the RTD is permitted to
deviate from the standard curve. Two conformity components: one tolerance to the reference temperature, normally 0°C,
and one tolerance on the slope. These possible gaps are defined by known standards. For example, the norme DIN 43760 class
B, requires the calibration from 0,12Ω (0.3°C) at 0°C, but permits the curve to move away from the nominal
0,00385 by ±0.000012 Ω/Ω/°C. This can result in a difference of 0.8°C at 100° C, 1.3°C
at 200°C, and up to 3.8°C at 700° C. It is therefore important to know with precision, the average tolerances
used.
Self Heating

The RTD is a passive sensor, it requires the passage of a measurement current to produce a useful signal. This current
heats the element and raises it's temperature. Errors will result if the sensor does not absorb the additional heat.
Self Heating is expressed in mW/°C, which is the power in milliwatts (1000.RI2) which
raises the internal temperatureof the sensor by 1°C. The higher the mW/°C, the less the phenomen is important.
For example, suppose a measurement current of 5 mA in a PT100 sensor in a 100°C ambient temperature. The specifications
indicate 50mW/°C in water displaces at 1m/sec. The quantity of heat produced is: 1000 mW * (0,005 A) * (18,5) = 3,5 mW;
the self heating error is (3,5 mW) / (50 mW/°C) = 0.07°C.
Modern measuring practices use very low currents, 100µA and sometimes lower. This practice, if used in the above
example, would give an elevated temperature error of only (0.00138 mW)/(50 mW/°C) = 0,000027°C, which is negligable.
The resulting error is inversely proportional to the capacity of the sensor to evacuate the additional heat. This depends
on materials, construction, and environment of the sensor. The worst case for this product is there is a high resistance
value in a small bodied construction. RTD film, with a small surface area to absorb the heat, is an example. Self heating
depends equally on where the sensor is immersed. The error in non-moving air can be 100 higher than that of running water.
Response Time

A time constant indicates the responce of an RTD to change in temperature. A common expression is the time it takes a
sensor to reach 63,2% of the temperature grade of moving water. The response time depends on the mass of the sensor and
the rate of thermal transfer between the external surface of the element and the environment in which it is immersed. A
small time constant reduces errors in systems that are subject to rapid temperature changes.
Temperature Calculations

Callendar-Van-Dusen (CVD) Equation

The relationship between the temperature and ohmic value of RTD's were calculated by Callendar, and later on, refined by
Van Dusen; this is why the equation is named Callendar-Van Dusen.

With RT = resistance at T°C, R0 = resistance at 0°C, α = temperature coefficient at 0°C in
Ω/Ω/°C, δ = linearisation coefficient, β = second coefficient of linearisation for
negatives temperature values (β = 0 for T > 0°C).
This equation has been transformed in order to be used easily with the coefficients A, B and C given by the standard
DIN 43760 (IEC 751) and the component technicals specifications with the following conversions:
With the following conversions :

| Different Coefficients for α (alpha) |
| Coefficient |
Value |
Value |
Value |
| α |
0,003850 |
0,003926 |
0,003911 |
| δ |
1,4999 |
|
|
| β |
0,10863 |
|
|
| A |
3,9083e-3 |
3,9848e-3 |
3,9692e-3 |
| B |
-5,775e-7 |
-5,870e-7 |
-5,8495e-7 |
| C |
-4,18301e-12 |
-4,000e-12 |
-4,2325e-12 |
These three values represent the three principal specifications for RTD's.
1. 0,003850 Ω/Ω/°C: Standard DIN 43760, IEC 751, named Europeen Industrial Standard.
2. 0,003926 Ω/Ω/°C: Require pur platinum (99,999%), named U.S. Industrial Standard.
3. 0,3911 Ω/Ω/°C: Often named U.S. Industrial Standard.
The Callendar-Van Dusen equation permits a good linearity of RTD's, ±0.01°C between -100°C
and +100°C but the error increases rapidly with high temperatures. Furthermore, this equation calculates
the resistance with temperature change; which is the opposite of the most current uses : Temperature with
resistance change.
To convert the resistance value of the RTD to temperature, we are obliged to use a quad equation to the 2nd degree,
which is, in sort, the reciprocal of the Callendar-Van Dusen equation, but iniquely for temperatures superior to 0°C.

For temperatures inferior to 0 C, the Callendar-Van Dusen equation is too complex to reslove and the the use of
successive approximations is necessary:

The following table propose calculated values with the Callendar-Van Dusen equation.
| Temperatures from resistance |
| Resistance (Ω) |
CVD Equation (°C) |
Error (%) |
| 10.00 |
-219.539 |
0.056 |
| 15.00 |
-208.114 |
0.073 |
| 20.00 |
-196.572 |
0.032 |
| 25.00 |
-184.918 |
0.024 |
| 30.00 |
-173.158 |
0.023 |
| 50.00 |
-125.602 |
0.383 |
| 75.00 |
-63.329 |
-0.010 |
| 100.00 |
0.000 |
|
| 102.00 |
5.121 |
-0.024 |
| 103.00 |
7.685 |
-0.022 |
| 107.79 |
19.991 |
-0.012 |
| 115.54 |
39.998 |
-0.009 |
| 120.00 |
51.566 |
-0.010 |
| 123.24 |
59.995 |
-0.011 |
| 130.90 |
80.008 |
-0.012 |
| 150.00 |
130.447 |
-0.017 |
| 175.00 |
197.673 |
-0.021 |
| 200.00 |
266.348 |
-0.027 |
| 210.00 |
294.246 |
-0.029 |
| 220.00 |
322.397 |
-0.031 |
| 250.00 |
408.450 |
-0.045 |
| 275.00 |
482.109 |
-0.048 |
| 300.00 |
557.688 |
-0.055 |
| 310.00 |
588.491 |
-0.058 |
| 399.00 |
879.278 |
-0.095 |
We can see that the gaps of the Callendar-Van Dusen equation are limited and are found around
0,05% and 0,1% for higher temperatures.
Advantages and Disadvantages

The major advantages that an RTD has over Thermocouples are: Stability, Precision, and Repeatability. The disadvantages are
the price and response time. The following table explains in more detail.
| Sensor |
Advantages |
Disadvantages |
| Thermocouple |
• Simple
• Inexpensive
• Large variety
• Large temperature range
• Rugged
• « Self-powered » |
• Non linear
• Low voltage
• Require reference
• Less stable |
| RTD |
• More Stable
• More accurate
• More linear |
• Expensive
• Current source required
• Small
• Self heating
• Small base resistance |
| Criteria |
Thermocouple |
RTD |
| Cost |
Low |
High |
| Temperature range |
Very large -450 à 4200 F |
Large -400 à 1200 F |
| Interchangeability |
Good |
Excellent |
| Long term Stability |
Fair |
Good |
| Accuracy |
Medium |
High |
| Sensibility (Output) |
Low |
Medium |
| Sensibility (tip) |
Excellent |
Fair |
| Response time |
Medium to fast |
Medium |
| Linearity |
Fair |
Good |
| Self heating |
None |
Low |
| Extension cable effect |
High |
Medium |
| Sensor dimension |
Very small to very large |
Small to medium |
Stability is the ability of a sensor to measure temperature with precision for a given length of time.
Repeatability characteristics of a temperature sensor represents the ability of the sensor to keep the same
physical behaviour for any give temperature even though it has been used and exposed to different temperatures.
In other words, it's ability to conserve it's stability even after many heating and cooling cycles.
Precision and Tolerances (Compared to Thermocouples)

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